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Mechanism of LigFG -aryl ether cleavage. GSH, reduced glutathione;... | Download Scientific Diagram

Redox imbalance and oxidative stress One of the major consequences of NADH/NAD + redox imbalance is oversupply of electron donors to the mitochondrial electron transport chain.26 Oversupply of NADH would overwhelm complex I, which relays electrons from NADH to CoQ.32 One feature of complex I electron transport is that the more electrons it transports, the more superoxide it will produce.103, 104, 105, 106 This is because more electrons could leak and partially reduce oxygen, leading to overproduction of superoxide which is the precursor of all the ROS.107, 108, 109, 110 Hence, oversupply of NADH in diabetes driven by constant hyperglycemia can devastate cells with enhanced oxidative stress, impaired mitochondrial function, and increased cell death, as has been demonstrated by numerous investigators.17, 27, 28, 111, 112, 113, 114, 115, 116, 117, 118 2.9

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